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Some Considerations Of Surface Preparation Before lonitriding®*

Author: George Idriceanu**

 
The increased use of metalformed and plastic products has created more attention to the surface treatments available for tools and machinery components. The increased life provided by lonitriding allows users to take advantage of significant savings during the manufacturing processes.
 
This paper presents some considerations which can optimize the ability of the tool surface to take maximum advantage of this surface hardening treatment.
 
The surface of a tool must have a geometrical correct shape without any grinding cracks, remelt layer from EDM-ing and free of scratches, nicks, dents, pores, orange peels or pitting. The same factors influencing the polishability of a tool can affect the lonitriding results:
  1. Tool steel quality: cleanliness (slag inclusions, porosity, oxides, entrapments, etc.), particles or areas with different properties or hardnesses.
  2. Heat treatment: soft spots, surface oxidation, decarburization, alloy depletion, etc.
  3. Polishing technique: smearing, overlapping, overpolishing (orange peel, pitting, overheating, etc.).
  4. Surface contamination: cutting fluids, drawing compounds, solid films and embedded particles from worn cutters and abrasives blended with metallic and non- metallic powders, binders, mold releases, oils, solvents, waxes and rust preventives.

The lonitriding process produces hardened case depths of .010" to .025" (.25mm to .60mm) on most mold and tool steels with a surface hardness of 60-65 HRC and higher. Due to the ceramic nature of the nitrides, the wear and corrosion resistance, antigalling and antiscoring properties as well as many others (fatigue life, compressive strength, etc.) are greatly improved.
 
lonitriding is a clean and environmentally safe process performed under vacuum in a controlled atmosphere at relatively low temperatures (750° to 1040°F or 400° to 560°C) with no quenching required. The process itself does not produce any stresses or dimensional changes, unless they were introduced from the previous operations (heat treatment, machining, polishing). The stress relieving effect which occurs during lonitriding would allow these stresses to be released.
 
Unknown surface contaminants may act like masking agents and they could affect the ability of the nitrogen ions to penetrate and diffuse into the steel.
 
Many surface contaminants must be removed prior to lonitriding since they will burn or decompose at processing temperature and may leave marks or solid residues on the surface.
 
The increased use of synthetic cutting fluids and rust preventives containing organic and/or inorganic chemicals (polymers, waxes, lacquers, metallic soaps, dry lubricants based on graphite, oxides or sulfates) are very difficult to be removed if allowed to dry on the surface after machining.
 
Sun Steel Treating Inc. is committed to work with each customer and application to identify and remove detrimental contaminants. Most contaminants can be removed by one or a combination of the following processes:

  1. Glass beading and/or vapor blasting. They also help in reducing lapping and smearing effects prior to lonitriding (mechanical polishing may promote blending of organic and inorganic particles in an adherent surface layer). After lonitriding. the surface can be further polished to the desired finish, knowing that the higher the surface hardness the better the polishability.
  2. Stress relieving at 950° to 1000°F (510° to 540°C), followed by glass beading or polishing.
  3. Depending on the contaminant chemistry, many can be removed through certain specific cleaning procedures.
  4. Clean and wash the parts immediately after the final machining/polishing and protect the surface with a water displacing oil (like WD40).

 
A good finish grind or surface finish of no less than 12 microns or up to 400-600 paper, prior to lonitriding is advisable. We prefer a lapping or polishing operation not be performed before the process (especially for parts with a hardness less than 35 RC). After lonitriding it is easy to achieve the desired finish by conventional methods.
 
Also, we would like to be informed about any surface defects revealed after final machining or during polishing and the method used to correct the problem (removal by deeper grinding/polishing, torching and pinning, micro welding, etc.). This information is needed for correct processing since these spots, laps or smeared films do not have the same metallurgical strength as the original material, and they may reopen during lonitriding.
 
These surface preparation methods and recommendations will assure the highest surface quality after the lonitriding process.
 
Our commitment to quality and service has earned us accreditation by NSF International Strategic Registrations to ISO 9001:2000.
 
For more information and technical assistance please contact Sun Steel Treating Inc., Technical Services.
 
* lonitriding is a surface hardening process for metals.
** George Idriceanu, Director of Research and Development, and Process Engineering, Sun Steel Treating Inc.